Modern chemical synthesis techniques have allowed for improved incorporation of nano‐scale additives into solid propellants. Various. Kumar Ishitha, P. A. Ramakrishna. () Activated charcoal: as burn rate modifier and its mechanism of action in non-metalized composite solid propellants. The combustion of hydroxyl-terminated polybutadiene (HTPB) propellants containing ne ammonium perchlo- rate (AP) was investigated using laser-excited, .

Author: Malasar Kill
Country: Montenegro
Language: English (Spanish)
Genre: Finance
Published (Last): 26 February 2017
Pages: 189
PDF File Size: 14.29 Mb
ePub File Size: 17.77 Mb
ISBN: 823-9-91741-912-5
Downloads: 43898
Price: Free* [*Free Regsitration Required]
Uploader: Zolokinos

The addition of burning rates catalysts like Ytpb 2 O 3 on the propellant formulation alters the thermal decomposition behavior of AP, and consequently the thermal decomposition behavior of the propellant. Several geometric configurations are often used depending on the application and desired thrust curve:. In addition, the high-power rocketry community regularly uses APCP in the form of commercially available propellant propellantd, as well as single-use motors. The combustion simulation results may be observed in the figure below, which show the behavior of AP combustion with different internal pressures of the combustion chamber.

Xiao-Bin [ 25 ] showed that the burning rates of propellants were very closely related to the exothermic peak temperature of ammonium nitrate AN that is used as an oxidizer in smokeless propellant formulation.

In btpb to this criteria, in this study, high heating rates were used For practical purposes the Arrhenius parameters, like the corrected reaction order, can be used to estimate the overall rate constant k for thermal decomposition using the eq.

Ammonium perchlorate composite propellant – Wikipedia

Minimum signature propellants contain primarily nitrogen-rich organic molecules e. In recent years, there has been an explosion of interest in the synthesis, structure, properties, and applications of nanomaterials, mainly because of the fact that materials confined in one or more dimension can exhibit interesting properties, such as catalysis. Several propeklants of heat releasing, thermal decomposition by DSC, combustion heat in oxygen environment, and explosion heat propellaants nitrogen environment, are characterized to learn the effect of dispersibility of nano-CuO catalyst on heat releasing of propellants.


These conditions are necessary because differences in the raw materials, as ammonium perchlorate AP particle size, can affect the thermal decomposition behavior of the composite. Ammonium perchlorate composite propellant APCP is a modern solid-propellant rocket used in rocket vehicles.

That is to say, after 3 hours kneading, the dispersibility of nano-CuO catalyst in propellant is improved to a maximum by kneading method. In addition, curing additives induce elastomer binder cross-linking to solidify the propellant before use.

The aging process is one of the most significant factors responsible for changes in the activation energy of solid propellants usually reduction. As a result of the development of nanotechnology, researches on nanocatalysts, including nanometer CuO, are surged up. Therefore, the materials may suffer many different changes in their structure or properties.

November 11th Reviewed: This first approach requires at least three determinations at different heating rates Fig. The motor casing and closures are typically bought separately from the motor manufacturer thpb are often precision-machined from aluminum.

With the same above assumptions, the Kissinger method 8 may be used to calculate the activation energy and the pre-exponential factor from the maximum rate condition which will occur at the maximum exothermic peak temperature, T p.

Catalysts always play a key role in heat releasing procedure of propellant. These parameters are the activation energy, Ea, and the pre-exponential factor, A, relatives to the decomposition process.

As the particle radius increases the volume and, therefore, mass and heat capacity increase as the cube of the radius. The references used may be made clearer with a different or consistent style of citation and footnoting. In addition, colored formulations are available to display reds, greens, blues, and even black smoke.


Use of APCP outside hobby use is regulated by state and municipal fire codes. They were both derived from the basic kinetic equations for heterogeneous chemical reactions and therefore have a wide application, as it is not necessary to know the reaction order [ 19 propeklants or the conversional function to determine the kinetic parameters.

Subscribe to Table of Contents Alerts.

Repository hosted by TU Delft Library

September Learn how and when to remove this template message. Having in account such assumptions, eq. The DSC curves show that the first propellnats is endothermic and the second stage is exothermic.

This is an open access article distributed under the Creative Commons Attribution Licensewhich permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Ammonium perchlorate composite propellant is typically used in aerospace propulsion applications, where simplicity and reliability are desired and specific impulses depending on the composition and operating pressure of — seconds are adequate.

The Ozawa method is one of the most popular methods for estimating activation energies by linear heating rate and it is the so-called isoconversional method.

These oxygen molecules will be used as oxidizer in binders combustion, when the AP is used in a composite propellant or even when is burning by itself.